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Introductory Organic Chemistry - Lecture 32

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Lecture 32 - Stereotopicity and Baeyer Strain Theory

Why ethane has a rotational barrier is still debatable. Analyzing conformational and configurational stereotopicity relationships among constitutionally equivalent groups reveals a subtle discrimination in enzyme reactions. When Baeyer suggested strain-induced reactivity due to distorting bond angles away from those in an ideal tetrahedron, he assumed that the cyclohexane ring is flat. He was soon corrected by clever Sachse, but Sachse's weakness in rhetoric led to a quarter-century of confusion.

Prof. J. Michael McBride
CHEM 125: Freshman Organic Chemistry, Fall 2008
(Yale University: Open Yale)
http://oyc.yale.edu
Date accessed: 2009-11-11
License: Creative Commons BY-NC-SA

Lecture Material

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Supplementary lecture material is listed below.

1. Topicity: Prochirality and Dehydrogenase



 

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